Standard

BS ISO 13914:2023

Soil, treated biowaste and sludge. Determination of dioxins and furans and dioxin-like polychlorinated biphenyls by gas chromatography with high resolution mass selective detection (HR GC-MS)

Current, Under Review

•

Published:

28 Feb 2023

1 Scope

This document specifies a method for quantitative determination of 17 2,3,7,8-chlorine substituted dibenzo-p-dioxins and dibenzofurans and dioxin-like polychlorinated biphenyls in sludge, treated biowaste and soil using liquid column chromatographic clean-up methods and GC/HRMS.

The analytes to be determined with this document are listed in Table 1.

Table 1 — Analytes and their abbreviations

Substance	Abbreviation
Tetrachlorodibenzo-p-dioxin	TCDD
Pentachlorodibenzo-p-dioxin	PeCDD
Hexachlorodibenzo-p-dioxin	HxCDD
Heptachlorodibenzo-p-dioxin	HpCDD
Octachlorodibenzo-p-dioxin	OCDD
Tetrachlorodibenzofuran	TCDF
Pentachlorodibenzofuran	PeCDF
Hexachlorodibenzofuran	HxCDF
Heptachlorodibenzofuran	HpCDF
Octachlorodibenzofuran	OCDF
Polychlorinated biphenyl	PCB
Trichlorobiphenyl	TCB
Tetrachlorobiphenyl	TeCB
Pentachlorobiphenyl	PeCB
Hexachlorobiphenyl	HxCB
Heptachlorobiphenyl	HpCB
Decachlorobiphenyl	DecaCB

The limit of detection depends on the kind of sample, the congener, the equipment used and the quality of chemicals used for extraction and clean-up. Under the conditions specified in this document, limits of detection better than 1 ng/kg (expressed as dry matter) can be achieved.

This method is “performance based”. The method can be modified if all performance criteria given in this method are met.

NOTE In principle, this method can also be applied for sediments, mineral wastes and for vegetation. It is the responsibility of the user of this document to validate the application for these matrices. For measurement in complex matrices like fly ashes adsorbed on vegetation, it can be necessary to further improve the clean-up. This can also apply to sediments and mineral wastes.

BSI recommends this version of standard for organisations operating in or with the UK. The ISO edition is available here if required.

Product Details

Descriptors

Chemical analysis and testing

Chromatography

Determination of content

Gas chromatography

Polychlorinated biphenyls

Soiling tests

Soils

Sludge

Wastes

ICS Codes

13.080.10 Chemical characteristics of soils

Committee

EH/4

International relationships

Identical to:

ISO 13914

ISBN

978 0 539 15990 5

Publisher

BSI