BS 7393 specifies a semi-micro colour indicator titration method for the determination of acidic constituents in new or used petroleum products and lubricants soluble in mixtures of toluene and isopropyl alcohol, or capable of existing as suspensions in such mixtures.
The method is especially intended for applications in which the amount of sample available to be analyzed is too small to allow accurate analysis by ISO 6619 or ISO 6618.
BS 7393 is applicable to the determination of acids having dissociation constants in water larger than 10–9. Extremely weak acids having dissociation constants smaller than 10–9 do not interfere. Salts titrate if their hydrolysis constants are larger than 10–9.
Note 1: Some oils, such as many cutting oils, rustproofing oils, An+d similar compounded oils, or excessively dark-coloured oils, may be more difficult to analyze by this method due to the obscurity of the colour indicator end-point. These oils can be analyzed by ISO 6619 provided sufficient sample is available. However, this situation is much less likely using BS 7393 than using ISO 6618, due to the use of a more highly dilute sample during the titration and due to the greater stability of the end-point colour change. The acid numbers obtained by this method may or may not be numerically the same as those obtained by ISO 6619, but they should be of the same order of magnitude.
Note 2: The results obtained using this method have been found to be numerically the same as those obtained using ISO 6618, within the precision of the two methods, for new or oxidized lubricants of the type primarily intended for hydraulic or steam turbine type service. The oxidized lubricants were obtained using ISO 4263. This correlation is shown by the correlation coefficient r = 0,989, with slope s = 1,017 and intercepts y = + 0,029, calculated using the total acid numbers obtained using both titration methods for the samples used for the precision statement (see 9.2).
BS 7393 on determination of total acid number in petroleum products by semi-micro colour indicator titration is useful for:
The total acid number is the quantity of KOH, expressed in milligrams, required to titrate all acids or salts present in one gram of the sample having dissociation or hydrolysis constants larger than 10–9.
Since the test method specified in BS 7393 requires substantially less sample than ISO 6618 or ISO 6619, it provides an advantageous means of monitoring an oxidation test by changes in total acid number by
The method specified in BS 7393 may be used to indicate relative changes in total acid number that occur in an oil during use under oxidizing conditions. Although the titration is made under definite equilibrium conditions, the method does not measure an absolute acidic property that can be used to predict the performance of an oil under service conditions. No general relationship between bearing corrosion and acid number is known.
BS 7393 also provides information about reagents and materials, preparation of used oil samples along with the schematic drawing of typical apparatus for carrying out test method.
Overall, BS 7393 provides guidance on carrying out semi-micro colour indicator titration for the determination of total acid number in petroleum products with precision and accuracy.
ISO 7537:1989