This document specifies the procedure for a quantitative determination of major and trace element concentrations in homogeneous solid waste, soil, soil-like material and sludge by energy dispersive X-ray fluorescence (EDXRF) spectrometry or wavelength dispersive X-ray fluorescence (WDXRF) spectrometry using a calibration with matrix-matched standards.
This document is applicable for the following elements: Na, Mg, Al, Si, P, S, Cl, K, Ca, Ti, V, Cr, Mn, Fe, Co, Ni, Cu, Zn, As, Se, Br, Rb, Sr, Y, Zr, Nb, Mo, Ag, Cd, Sn, Sb, Te, I, Cs, Ba, Ta, W, Hg, Tl, Pb, Bi, Th and U. Concentration levels between a mass fraction of approximately 0,000 1 % and 100 % can be determined depending on the element and the instrument used.
An optional XRF screening method for solid and liquid material as waste, sludge and soil is added in Annex A which provides a total element characterization at a semi-quantitative level, where the calibration is based on matrix-independent calibration curves, previously set up by the manufacturer.
BSI recommends this version of standard for organisations operating in or with the UK. The ISO edition is available here if required.